8.-REVIEW OF THE EFFECT OF CHARCOAL COMBUSTION ON HEALTH AND ENVIRONMENT

In 2014, about 53 million tonnes of wood charcoal were produced worldwide, this number
unsurprisingly keeps increasing especially in African countries like Nigeria, this is due to a lack
of electricity, high inflation, and expensive cleaner cooking utilities. Household applications of
charcoal include; Cooking, Barbeque grilling, Pressing iron, charcoal incense burning, and room
warmer. This paper studies the aforementioned ways of charcoal application that produces
greenhouse gases and energy through anthropogenic emissions/formation of various pollutants
such as heat, carbon monoxide, carbon dioxide, polyaromatic hydrocarbons, nitrogen dioxide,
particulate matter, methane, ozone, which affect health and climate at large. By Studying an
overview of the mechanism of emission of these pollutants, this review explained more about health
and environment concerning greenhouse gases emitted during charcoal combustion, as well as
the role of charcoal in the temperature rise, effects of charcoal emitted gases on climate such as
Global warming, effects of charcoal emitted gases on health such cancer, seizure, and stroke,
effects of charcoal emitted gases on nutrition and coral reef survival. Element such as high
temperature, elevated Co2, and precipitation greatly impact plant growth and nutrient. There is a
particularly critical need for action and awareness in sub-Saharan Africa, where population
growth has outpaced access to clean cooking.

9.-ON THE ISSUE OF THE RESTART TIME OF A CORE ANNULAR FLOW OIL PIPELINE AFTER SHUT-DOWN OPERATIONS

There is a growing number of proposed models for the estimation of the time needed to restart a
core annular flow line after shutting down, pertaining the improvement of core annular flow (CAF)
technology for transportation of high viscous oil. Existing restart time models tend to predict that
the flow line needs to be completely clean. However, this is practically not feasible. Firstly, this
work revisits the results of the flow pattern trends and pressure drop evolutions during the restart
of a core annular flow experiments. Based on the analyses of the transient pressure drop profiles,
deduction of a ‘realistic and economical’ re-start time, expressed as a function of the pressure
drop, has been made. This approach can be helpful in control engineering design of an efficient
and cost-effective re-start process of a core annular flow (CAF) line.

10.-A PRELIMINARY EVALUATION OF THE INDEPENDENT STATUS OF REGULATORY INSTITUTIONS IN NIGERIA’S PETROLEUM INDUSTRY ACT 2021

Oil and Gas have become an integral part of today’s global economy and a key component of
many national economies including Nigeria and the nature of institutional, legal and regulatory
framework tends to have significant economic, developmental, and strategic outcomes. Nigeria’s
Oil and Gas industry which has, for most of her independence been the mainstay of the economy,
has been operated in opaque manner resulting in the failure to be a significant contributor to
Nigeria’s development. The enactment of a new overarching law – the Petroleum Industry Act,
2021 (PIA) promises to give impetus towards a more virile industry. Central to the thriving of the
new law is a regulatory framework that would balance the often conflicting and mutually exclusive
interests of government, the investor and the consumer. To achieve this however, the institutional
design and architecture of the regulatory institutions must be woven in a fabric of independence:
independent from all the players in the value chain. This Paper seeks to undertake an evaluation
of the de jure independent status of the regulatory institutions in the PIA, and suggest pathways
for improvement towards global best practices.

1.-Cover-Page.

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2.-Masthead

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6.-Optimized Biodiesel Production from Waste Cooking Oil Using Poultry Droppings Catalyst: A Comparison of RSM and Ann

This study developed a catalyst from poultry droppings for the synthesis of biodiesel from waste
cooking oil (WCO). Poultry droppings catalyst characterization was achieved using Brunauer-Emmett and Teller (BET) analysis, fourier transform infrared spectroscopy (FTIR), scanning electron microscope and energy dispersive X-ray (SEM-EDX), X-ray fluorescence (XRF), and Xray diffraction (XRD). Box-Behnken design (BBD) was used in designing the experiments. Response surface methodology (RSM) and artificial neural network (ANN) were compared to determine their performance in modelling and optimizing the process. The catalysts
characterization revealed CaO as the largest constituent and the presence of high surface area (286.322m2/g) and pore size (1.853nm). Optimum biodiesel yield of 90.4694% was achieved with a temperature of 43.92℃, reaction time of 120 minutes with a methanol/oil ratio of 6:1 and catalyst loading of 1 wt.%. RSM model was found to be very efficient with R2 value of 0.9464. Although, comparing with ANN, ANN performed better with a higher R2 value of 0.99669.

7.-Effect of Catalyst Modification on Biodiesel Production from Waste Vegetable Oil

The promising catalytic properties of calcium oxide from eggshell makes it desirable as a
heterogeneous catalyst for the production of biodiesel from waste oil. This study investigated the
effect of modifying plain calcium oxide from chicken eggshells on the transesterification of waste
vegetable oil to biodiesel. Using the American Standard Testing Methods (ASTM D6 751-03,
2003), acid value, free fatty acid, density, and viscosity analysis were performed on the waste
vegetable oil after cleaning. Free fatty acid reduction was done by esterifying the oil with 0.5wt%
tetraoxosulphate IV acid in a 1000ml round-bottomed flask. The round-bottomed flask was
mounted on a magnetic stirrer having a speed of 650rpm with the reaction temperature set to
60°C. Eggshell as parent catalyst was modified with zinc oxide and titania and the experiment
was performed at different catalyst loading. The biodiesel produced with different catalysts
modification and loadings was analyzed with Gas Chromatography-Mass Spectrometry. The free
fatty acid of the oil which was originally 6.875% was reduced to 2.404%. Also, a maximum
biodiesel yield of 75.52% was obtained with plain eggshell at 4wt% catalyst loading. The acid
value, density, viscosity, flash point, pour point, and cloud point of the biodiesel produced were
1.122mgKOH/g, 878kg/m3, 5.82cSt, 118°C, -1.1°C, and 1.7°C respectively.

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